Chiefs of Mission for Mali
- Donald Albert Dumont (1960-)
- Henry Serrano Villard (1960-)
- Thomas Kenneth Wright (1960-1961)
- William Jules Handley (1961-1964)
- Charles Robert Moore (1965-1968)
- Gilbert Edward Clark (1968-1970)
- Robert Orris Blake (1970-1973)
- Ralph Jack McGuire (1973-1976)
- Patricia Mary Byrne (1976-1979)
- Anne Forrester Holloway (1979-1981)
- Parker W. Borg (1981-1984)
- Robert J. Ryan (1984-1987)
- Robert Maxwell Pringle (1987-1990)
- Herbert Donald Gelber (1990-1993)
- William H. Dameron (1993-1995)
- David P. Rawson (1995-1999)
- Michael Edward Ranneberger (1999-2002)
- Vicki J. Huddleston (2002-2005)
- Terence Patrick McCulley (2005-2008)
- Gillian Arlette Milovanovic (2008-2011)
- Mary Beth Leonard (2011-)
- Carolee Heileman (-)