2005 - Principals and Chiefs Chronological
Listing - People - Department History
Principal Officers and Chiefs of Mission, by Year: 2005
NOTE TO READERS
Updates to the Principal Officers and Chiefs of Mission database are currently suspended. For information about the Department’s current and recent leadership, we recommend visiting the Department of State homepage’s Biographies of Senior Officials and List of U.S. Ambassadors.
Notice posted on January 12, 2024.
Last
updated March 14, 2024.
Note: Career Foreign Service appointees are asterisked.
- Eduardo Aguirre (1946–)
- Ambassador Extraordinary and Plenipotentiary, Andorra (2005–2009)
- Ambassador Extraordinary and Plenipotentiary, Spain (2005–2009)
- *Michael R. Arietti (1947–)
- Ambassador Extraordinary and Plenipotentiary, Rwanda (2005–2008)
- Richard Lee Armitage (1945–)
- Deputy Secretary of State (2001–2005)
- Assistant Secretary of State for East Asian and Pacific Affairs (Nomination withdrawn.)
- Victor Henderson Ashe (1945–)
- Ambassador Extraordinary and Plenipotentiary, Poland (2004–2009)
- Roy L. Austin (1939–)
- Ambassador Extraordinary and Plenipotentiary, Trinidad and Tobago (2001–2009)
- Catherine Todd Bailey (1951–)
- Ambassador Extraordinary and Plenipotentiary, Latvia (2004–2008)
- Howard Henry Baker Jr. (1925–2014)
- Ambassador Extraordinary and Plenipotentiary, Japan (2001–2005)
- *Richard L. Baltimore III (1947–)
- Ambassador Extraordinary and Plenipotentiary, Oman (2002–2006)
- Hugh Douglas Barclay (1932–)
- Ambassador Extraordinary and Plenipotentiary, El Salvador (2003–2007)
- Marsha E. Barnes (1947–)
- Ambassador Extraordinary and Plenipotentiary, Suriname (2003–2006)
- *Joyce A. Barr (1951–)
- Ambassador Extraordinary and Plenipotentiary, Namibia (2004–2007)
- Assistant Secretary of State for Administration (2011–2017)
- *William M. Bellamy (1950–)
- Ambassador Extraordinary and Plenipotentiary, Kenya (2003–2006)
- John B. Bellinger 3rd (1960–)
- Legal Adviser (2005–2009)
- Jeffrey Thomas Bergner (1946–)
- Assistant Secretary of State for Legislative Affairs (2005–2008)
- Stuart A. Bernstein (1938–)
- Ambassador Extraordinary and Plenipotentiary, Denmark (2001–2005)
- *Gregory L. Berry (1951–)
- Principal Officer, Libya (2006)
- Chargé d’Affaires ad interim, Libya (2006)
- *John Ross Beyrle (1954–)
- Ambassador Extraordinary and Plenipotentiary, Bulgaria (2005–2008)
- Ambassador Extraordinary and Plenipotentiary, Russia (2008–2012)
- Miles Teel Bivins (1947–2009)
- Ambassador Extraordinary and Plenipotentiary, Sweden (2004–2006)
- *John William Blaney (1948–)
- Ambassador Extraordinary and Plenipotentiary, Liberia (2002–2005)
- Lincoln P. Bloomfield (1952–)
- Assistant Secretary of State for Politico-Military Affairs (2001–2005)
- John R. Bolton (1948–)
- Assistant Secretary of State for International Organization Affairs (1989–1993)
- Under Secretary of State for Arms Control and International Security Affairs (2001–2005)
- Representative of the U.S.A. to the United Nations (2005–2006)
- *Donald E. Booth (1954–)
- Ambassador Extraordinary and Plenipotentiary, Liberia (2005–2008)
- Ambassador Extraordinary and Plenipotentiary, Zambia (2008–2010)
- Ambassador Extraordinary and Plenipotentiary, Ethiopia (2010–2013)
- Molly Hering Bordonaro (1968–)
- Ambassador Extraordinary and Plenipotentiary, Malta (2005–2009)
- *Richard A. Boucher (1951–)
- Ambassador Extraordinary and Plenipotentiary, Cyprus (1993–1996)
- Assistant Secretary of State for Public Affairs (2000–2005)
- Assistant Secretary of State for South and Central Asian Affairs (2006–2009)
- Career Ambassador (2008)
- *Ralph Leo Boyce (1952–)
- Chargé d’Affaires ad interim, Singapore (1994)
- Ambassador Extraordinary and Plenipotentiary, Indonesia (2001–2004)
- Ambassador Extraordinary and Plenipotentiary, Thailand (2004–2007)
- *Aurelia Erskine Brazeal (1943–)
- Ambassador Extraordinary and Plenipotentiary, Micronesia, Federated States of (1990–1993)
- Ambassador Extraordinary and Plenipotentiary, Kenya (1993–1996)
- Ambassador Extraordinary and Plenipotentiary, Ethiopia (2002–2005)
- *Martin George Brennan (1949–)
- Ambassador Extraordinary and Plenipotentiary, Uganda (1999–2002)
- Ambassador Extraordinary and Plenipotentiary, Zambia (2002–2005)
- *Pamela E. Bridgewater Awkward (1947–)
- Ambassador Extraordinary and Plenipotentiary, Benin (2000–2002)
- Ambassador Extraordinary and Plenipotentiary, Ghana (2005–2008)
- Ambassador Extraordinary and Plenipotentiary, Jamaica (2010–2013)
- *Laurence G. Brown (1953–)
- Director of the Office of Medical Services (2003–2008)
- Lyons Brown Jr. (1936–)
- Ambassador Extraordinary and Plenipotentiary, Austria (2001–2005)
- *William R. Brownfield (1952–)
- Ambassador Extraordinary and Plenipotentiary, Chile (2002–2004)
- Ambassador Extraordinary and Plenipotentiary, Venezuela (2004–2007)
- Ambassador Extraordinary and Plenipotentiary, Colombia (2007–2010)
- Assistant Secretary of State for International Narcotics and Law Enforcement Affairs (2011–2017)
- Career Ambassador (2012)
- *Steven A. Browning (1949–)
- Ambassador Extraordinary and Plenipotentiary, Malawi (2003–2004)
- Ambassador Extraordinary and Plenipotentiary, Uganda (2005–2009)
- *Roland Wentworth Bullen (1944–)
- Ambassador Extraordinary and Plenipotentiary, Guyana (2003–2006)
- Christopher Bancroft Burnham (1956–)
- Assistant Secretary of State for Resource Management (2002–2005)
- *R. Nicholas Burns (1956–)
- Ambassador Extraordinary and Plenipotentiary, Greece (1997–2001)
- U.S. Permanent Representative on the Council of the North Atlantic Treaty Organization (2001–2005)
- Under Secretary of State for Political Affairs (2005–2008)
- *William Joseph Burns (1956–)
- Executive Secretary (1996–1998)
- Ambassador Extraordinary and Plenipotentiary, Jordan (1998–2001)
- Assistant Secretary of State for Near Eastern Affairs (2001–2005)
- Ambassador Extraordinary and Plenipotentiary, Russia (2005–2008)
- Under Secretary of State for Political Affairs (2008–2011)
- Career Ambassador (2008)
- Deputy Secretary of State (2011–2014)
- *Lawrence E. Butler (1953–)
- Ambassador Extraordinary and Plenipotentiary, Macedonia (2002–2005)
- William Cabaniss (1938–)
- Ambassador Extraordinary and Plenipotentiary, Czech Republic (2003–2006)
- James Cain (1957–)
- Ambassador Extraordinary and Plenipotentiary, Denmark (2005–2009)
- *John Campbell (1944–)
- Ambassador Extraordinary and Plenipotentiary, Nigeria (2004–2007)
- *James Caldwell Cason (1944–)
- Principal Officer, Cuba (2005)
- Ambassador Extraordinary and Plenipotentiary, Paraguay (2005–2008)
- Argeo Paul Cellucci (1948–)
- Ambassador Extraordinary and Plenipotentiary, Canada (2001–2005)
- Robert B. Charles (1960–)
- Assistant Secretary of State for International Narcotics and Law Enforcement Affairs (2003–2005)
- *Gene Burl Christy (1948–)
- Ambassador Extraordinary and Plenipotentiary, Brunei (2002–2005)
- Daniel Ray Coats (1943–)
- Ambassador Extraordinary and Plenipotentiary, Germany (2001–2005)
- Sue McCourt Cobb (1937–)
- Ambassador Extraordinary and Plenipotentiary, Jamaica (2001–2005)
- *Ryan Clark Crocker (1949–)
- Ambassador Extraordinary and Plenipotentiary, Lebanon (1990–1993)
- Ambassador Extraordinary and Plenipotentiary, Kuwait (1994–1997)
- Ambassador Extraordinary and Plenipotentiary, Syria (1998–2001)
- Chargé d’Affaires ad interim, Afghanistan (2002)
- Ambassador Extraordinary and Plenipotentiary, Pakistan (2004–2007)
- Career Ambassador (2004)
- Ambassador Extraordinary and Plenipotentiary, Iraq (2007–2009)
- Ambassador Extraordinary and Plenipotentiary, Afghanistan (2011–2012)
- Jack Dyer Crouch (1958–)
- Ambassador Extraordinary and Plenipotentiary, Romania (2004–2005)
- Henry Crumpton (1957–)
- Director of the Bureau of Counterterrorism (2005–2007)
- John Claggett Danforth (1936–)
- Representative of the U.S.A. to the United Nations (2004–2005)
- John J. Danilovich (1950–)
- Ambassador Extraordinary and Plenipotentiary, Costa Rica (2001–2004)
- Ambassador Extraordinary and Plenipotentiary, Brazil (2004–2005)
- Paula A. De Sutter (1958–)
- Assistant Secretary of State for Arms Control, Verification, and Compliance (2002–2009)
- *Scott H. DeLisi (1953–)
- Ambassador Extraordinary and Plenipotentiary, Eritrea (2004–2007)
- Ambassador Extraordinary and Plenipotentiary, Nepal (2010–2012)
- Ambassador Extraordinary and Plenipotentiary, Uganda (2012–2015)
- *Christopher William Dell (1956–)
- Ambassador Extraordinary and Plenipotentiary, Angola (2001–2004)
- Ambassador Extraordinary and Plenipotentiary, Zimbabwe (2004–2007)
- Ambassador Extraordinary and Plenipotentiary, Kosovo (2009–2012)
- *James Michael Derham (1947–)
- Ambassador Extraordinary and Plenipotentiary, Guatemala (2005–2008)
- Chargé d’Affaires, Venezuela (2013)
- Arthur E. Dewey (1933–)
- Assistant Secretary of State for Population, Refugees, and Migration Affairs (2002–2005)
- Robert J. Dieter (1946–)
- Ambassador Extraordinary and Plenipotentiary, Belize (2005–2009)
- *Larry Miles Dinger (1946–)
- Ambassador Extraordinary and Plenipotentiary, Micronesia, Federated States of (2001–2004)
- Ambassador Extraordinary and Plenipotentiary, Fiji (2005–2008)
- Ambassador Extraordinary and Plenipotentiary, Kiribati (2005–2008)
- Ambassador Extraordinary and Plenipotentiary, Tonga (2005–2008)
- Ambassador Extraordinary and Plenipotentiary, Nauru (2005–2008)
- Ambassador Extraordinary and Plenipotentiary, Tuvalu (2005–2008)
- Chargé d’Affaires, Burma (2011)
- Paula J. Dobriansky (1955–)
- Under Secretary of State for Civilian Security, Democracy, and Human Rights (2001–2009)
- *David B. Dunn (1949–)
- Ambassador Extraordinary and Plenipotentiary, Zambia (1999–2002)
- Ambassador Extraordinary and Plenipotentiary, Togo (2005–2008)
- *Alan Walter Eastham Jr. (1951–)
- Ambassador Extraordinary and Plenipotentiary, Malawi (2005–2008)
- Ambassador Extraordinary and Plenipotentiary, Congo (Brazzaville) (2008–2010)
- *William A. Eaton (1952–)
- Assistant Secretary of State for Administration (2001–2005)
- Ambassador Extraordinary and Plenipotentiary, Panama (2005–2008)
- *Eric S. Edelman (1951–)
- Ambassador Extraordinary and Plenipotentiary, Finland (1998–2001)
- Ambassador Extraordinary and Plenipotentiary, Turkey (2003–2005)
- *Cynthia Grissom Efird (1950–)
- Ambassador Extraordinary and Plenipotentiary, Angola (2004–2007)
- *Gregory W. Engle (1954–)
- Ambassador Extraordinary and Plenipotentiary, Togo (2003–2005)
- Donald Burnham Ensenat (1946–)
- Ambassador Extraordinary and Plenipotentiary, Brunei (1992–1993)
- Chief of Protocol (2001–2007)
- *Richard W. Erdman (1945–)
- Ambassador Extraordinary and Plenipotentiary, Algeria (2003–2006)
- *John Marshall Evans (1950–)
- Ambassador Extraordinary and Plenipotentiary, Armenia (2004–2006)
- *Jeffrey David Feltman (1959–)
- Ambassador Extraordinary and Plenipotentiary, Lebanon (2004–2008)
- Assistant Secretary of State for Near Eastern Affairs (2009–2012)
- Thomas Fingar (1946–)
- Assistant Secretary of State for Intelligence and Research (2004–2005)
- *Robert W. Fitts (1948–)
- Ambassador Extraordinary and Plenipotentiary, Solomon Islands (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Papua New Guinea (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Vanuatu (2003–2006)
- *James Brendan Foley (1957–)
- Ambassador Extraordinary and Plenipotentiary, Haiti (2003–2005)
- Ambassador Extraordinary and Plenipotentiary, Croatia (2009–2012)
- *Charles A. Ford (1950–)
- Ambassador Extraordinary and Plenipotentiary, Honduras (2005–2008)
- *Ralph Frank (1946–)
- Ambassador Extraordinary and Plenipotentiary, Nepal (1997–2001)
- Ambassador Extraordinary and Plenipotentiary, Croatia (2003–2006)
- Jendayi Elizabeth Frazer (1961–)
- Ambassador Extraordinary and Plenipotentiary, South Africa (2004–2005)
- Assistant Secretary of State for African Affairs (2005–2009)
- Russell F. Freeman (1939–)
- Ambassador Extraordinary and Plenipotentiary, Belize (2001–2005)
- *Daniel Fried (1952–)
- Ambassador Extraordinary and Plenipotentiary, Poland (1997–2000)
- Assistant Secretary of State for European and Eurasian Affairs (2005–2009)
- *James Irvin Gadsden (1948–)
- Ambassador Extraordinary and Plenipotentiary, Iceland (2002–2005)
- Antonio O. Garza Jr. (1957–)
- Ambassador Extraordinary and Plenipotentiary, Mexico (2002–2009)
- Grant S. Green (1938–)
- Under Secretary of State for Management (2001–2005)
- *David N. Greenlee (1943–)
- Ambassador Extraordinary and Plenipotentiary, Paraguay (2000–2003)
- Ambassador Extraordinary and Plenipotentiary, Bolivia (2002–2006)
- Richard J. Griffin (1949–)
- Director of the Office of Foreign Missions (2005–2007)
- Assistant Secretary of State for Diplomatic Security (2005–2007)
- *Marc Isaiah Grossman (1951–)
- Executive Secretary (1993–1994)
- Ambassador Extraordinary and Plenipotentiary, Turkey (1994–1997)
- Assistant Secretary of State for European and Eurasian Affairs (1997–2000)
- Director General of the Foreign Service (2000)
- Under Secretary of State for Political Affairs (2001–2005)
- Career Ambassador (2004)
- *Lino Gutierrez (1951–)
- Ambassador Extraordinary and Plenipotentiary, Nicaragua (1996–1999)
- Ambassador Extraordinary and Plenipotentiary, Argentina (2003–2006)
- *David Hale (1961–)
- Chargé d’Affaires ad interim, Jordan (2005)
- Ambassador Extraordinary and Plenipotentiary, Jordan (2005–2008)
- Ambassador Extraordinary and Plenipotentiary, Lebanon (2013–2015)
- Ambassador Extraordinary and Plenipotentiary, Pakistan (2015–2018)
- Under Secretary of State for Political Affairs (2018)
- Career Ambassador (2018)
- *Suzanne Hale (1948–)
- Ambassador Extraordinary and Plenipotentiary, Micronesia, Federated States of (2004–2007)
- Tony P. Hall (1942–)
- U.S. Representative to the United Nations Agencies for Food and Agriculture (Rome) (2002–2006)
- *John Randle Hamilton (1944–)
- Ambassador Extraordinary and Plenipotentiary, Peru (1999–2002)
- Ambassador Extraordinary and Plenipotentiary, Guatemala (2002–2005)
- John V. Hanford 3rd (1954–)
- Ambassador at Large (2002–2009)
- *Reno Leon Harnish III (1949–)
- Ambassador Extraordinary and Plenipotentiary, Azerbaijan (2003–2006)
- Patricia DeStacy Harrison (1939–)
- Assistant Secretary of State for Educational and Cultural Affairs (2001–2005)
- *Maura Ann Harty (1959–)
- Ambassador Extraordinary and Plenipotentiary, Paraguay (1997–1999)
- Executive Secretary (2001–2002)
- Assistant Secretary of State for Consular Affairs (2002–2008)
- *Patricia Marie Haslach (1956–)
- Ambassador Extraordinary and Plenipotentiary, Laos (2004–2007)
- Ambassador Extraordinary and Plenipotentiary, Ethiopia (2013–2016)
- Patricia Louise Herbold (1940–)
- Ambassador Extraordinary and Plenipotentiary, Singapore (2005–2009)
- *John Edward Herbst (1952–)
- Ambassador Extraordinary and Plenipotentiary, Uzbekistan (2000–2003)
- Ambassador Extraordinary and Plenipotentiary, Ukraine (2003–2006)
- Hans H. Hertell (1950–)
- Ambassador Extraordinary and Plenipotentiary, Dominican Republic (2001–2007)
- *Christopher Robert Hill (1952–)
- Chargé d’Affaires ad interim, Albania (1991)
- Ambassador Extraordinary and Plenipotentiary, Macedonia (1996–1999)
- Ambassador Extraordinary and Plenipotentiary, Poland (2000–2004)
- Ambassador Extraordinary and Plenipotentiary, Korea (2004–2005)
- Assistant Secretary of State for East Asian and Pacific Affairs (2005–2009)
- Ambassador Extraordinary and Plenipotentiary, Iraq (2009–2010)
- John Hillen (1966–)
- Assistant Secretary of State for Politico-Military Affairs (2005–2008)
- *Richard Eugene Hoagland (1950–)
- Ambassador Extraordinary and Plenipotentiary, Tajikistan (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Kazakhstan (2008–2011)
- Chargé d’Affaires ad interim, Turkmenistan (2008)
- Ambassador Extraordinary and Plenipotentiary, Armenia (Nomination of May 23, 2006, not acted upon by the Senate. Renominated January 9, 2007. Nomination withdrawn August 3, 2007.)
- *Heather M. Hodges (1946–)
- Ambassador Extraordinary and Plenipotentiary, Moldova (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Ecuador (2008–2011)
- Alfred Hoffman (1934–)
- Ambassador Extraordinary and Plenipotentiary, Portugal (2005–2007)
- *Karl William Hofmann (1961–)
- Chargé d’Affaires ad interim, Lesotho (1995)
- Ambassador Extraordinary and Plenipotentiary, Togo (2000–2002)
- Executive Secretary (2002–2005)
- *J. Anthony Holmes (1950–)
- Ambassador Extraordinary and Plenipotentiary, Burkina Faso (2002–2005)
- Kim R. Holmes (1952–)
- Assistant Secretary of State for International Organization Affairs (2002–2005)
- Henrietta Holsman Fore (1948–)
- Under Secretary of State for Management (2005–2007)
- *Aubrey Hooks (1948–)
- Ambassador Extraordinary and Plenipotentiary, Congo (Brazzaville) (1996–1999)
- Ambassador Extraordinary and Plenipotentiary, Congo (Kinshasa) (2001–2004)
- Ambassador Extraordinary and Plenipotentiary, Côte d’Ivoire (2004–2007)
- *Vicki J. Huddleston (1942–)
- Ambassador Extraordinary and Plenipotentiary, Madagascar (1995–1997)
- Principal Officer, Cuba (2002)
- Ambassador Extraordinary and Plenipotentiary, Mali (2002–2005)
- *William J. Hudson (1946–)
- Ambassador Extraordinary and Plenipotentiary, Tunisia (2003–2006)
- *Joseph Huggins (1951–)
- Ambassador Extraordinary and Plenipotentiary, Botswana (2002–2005)
- Karen P. Hughes (1956–)
- Under Secretary of State for Public Diplomacy and Public Affairs (2005–2007)
- *Thomas Neil Hull (1945–)
- Ambassador Extraordinary and Plenipotentiary, Sierra Leone (2004–2007)
- *Tracey Ann Jacobson (1965–)
- Ambassador Extraordinary and Plenipotentiary, Turkmenistan (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Tajikistan (2006–2009)
- Ambassador Extraordinary and Plenipotentiary, Kosovo (2012–2015)
- *Linda Jewell (1953–)
- Ambassador Extraordinary and Plenipotentiary, Ecuador (2005–2008)
- Brenda LaGrange Johnson (1939–)
- Ambassador Extraordinary and Plenipotentiary, Jamaica (2005–2009)
- *Donald C. Johnson (1949–)
- Ambassador Extraordinary and Plenipotentiary, Mongolia (1993–1996)
- Ambassador Extraordinary and Plenipotentiary, Cape Verde (2002–2005)
- Ambassador Extraordinary and Plenipotentiary, Equatorial Guinea (2006–2008)
- *A. Elizabeth Jones (1948–)
- Ambassador Extraordinary and Plenipotentiary, Kazakhstan (1995–1998)
- Assistant Secretary of State for European and Eurasian Affairs (2001–2005)
- Career Ambassador (2004)
- Ambassador Extraordinary and Plenipotentiary, Germany (Nomination of February 22, 2000, was not acted upon by the Senate.)
- *Richard Henry Jones (1950–)
- Ambassador Extraordinary and Plenipotentiary, Lebanon (1995–1998)
- Ambassador Extraordinary and Plenipotentiary, Kazakhstan (1998–2001)
- Ambassador Extraordinary and Plenipotentiary, Kuwait (2001–2004)
- Ambassador Extraordinary and Plenipotentiary, Israel (2005–2008)
- Robert Joseph (1949–)
- Under Secretary of State for Arms Control and International Security Affairs (2005–2007)
- *John F. Keane (1944–)
- Ambassador Extraordinary and Plenipotentiary, Paraguay (2002–2005)
- *Craig Allen Kelly (1953–)
- Ambassador Extraordinary and Plenipotentiary, Chile (2004–2007)
- James Andrew Kelly (1936–)
- Assistant Secretary of State for East Asian and Pacific Affairs (2001–2005)
- Paul Vincent Kelly (1947–)
- Assistant Secretary of State for Legislative Affairs (2001–2005)
- *Kristie Ann Kenney (1955–)
- Executive Secretary (1998–2001)
- Ambassador Extraordinary and Plenipotentiary, Ecuador (2002–2005)
- Ambassador Extraordinary and Plenipotentiary, Philippines (2006–2009)
- Ambassador Extraordinary and Plenipotentiary, Thailand (2010–2014)
- Career Ambassador (2012)
- Counselor (2016–2017)
- James Casey Kenny (1953–)
- Ambassador Extraordinary and Plenipotentiary, Ireland (2003–2006)
- Zalmay Khalilzad (1951–)
- Ambassador Extraordinary and Plenipotentiary, Afghanistan (2003–2005)
- Ambassador Extraordinary and Plenipotentiary, Iraq (2005–2007)
- Representative of the U.S.A. to the United Nations (2007–2009)
- *Michael Klosson (1949–)
- Ambassador Extraordinary and Plenipotentiary, Cyprus (2002–2005)
- *Jimmy J. Kolker (1948–)
- Ambassador Extraordinary and Plenipotentiary, Burkina Faso (1999–2002)
- Ambassador Extraordinary and Plenipotentiary, Uganda (2002–2005)
- Tom C. Korologos (1933–)
- Ambassador Extraordinary and Plenipotentiary, Belgium (2004–2007)
- *Thomas Charles Krajeski (1950–)
- Ambassador Extraordinary and Plenipotentiary, Yemen (2004–2007)
- Ambassador Extraordinary and Plenipotentiary, Bahrain (2011–2014)
- Mary Kramer (1935–)
- Ambassador Extraordinary and Plenipotentiary, Dominica (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Barbados (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Antigua and Barbuda (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Grenada (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Saint Vincent and the Grenadines (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Saint Lucia (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Saint Kitts and Nevis (2003–2006)
- Stephen Krasner (1942–)
- Director of Policy Planning (2005–2007)
- *George Albert Krol (1956–)
- Ambassador Extraordinary and Plenipotentiary, Belarus (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Uzbekistan (2011–2014)
- Ambassador Extraordinary and Plenipotentiary, Kazakhstan (2014–2018)
- Ambassador Extraordinary and Plenipotentiary, Turkmenistan (Nomination of June 27, 2007, withdrawn on April 28, 2008.)
- Howard J. Krongard (1940–)
- Inspector General of the Department of State and the Foreign Service (2005–2008)
- *Daniel Charles Kurtzer (1949–)
- Ambassador Extraordinary and Plenipotentiary, Egypt (1997–2001)
- Ambassador Extraordinary and Plenipotentiary, Israel (2001–2005)
- *Helen R. Meagher La Lime (1951–)
- Ambassador Extraordinary and Plenipotentiary, Mozambique (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Angola (2014–2017)
- *Christopher L. LaFleur (1949–)
- Ambassador Extraordinary and Plenipotentiary, Malaysia (2004–2007)
- Mark Langdale (1954–)
- Ambassador Extraordinary and Plenipotentiary, Costa Rica (2005–2008)
- *Alan Philip Larson (1949–)
- Representative of the U.S.A. to the Organization for Economic Cooperation and Development (Paris) (1990–1993)
- Assistant Secretary of State for Economic, Energy, and Business Affairs (1996–1999)
- Under Secretary for Economic Growth, Energy, and the Environment (1999–2005)
- Career Ambassador (2004)
- Franklin L. Lavin (1957–)
- Ambassador Extraordinary and Plenipotentiary, Singapore (2001–2005)
- Howard H. Leach (1930–)
- Ambassador Extraordinary and Plenipotentiary, France (2001–2005)
- *Joseph Evan LeBaron (1947–)
- Ambassador Extraordinary and Plenipotentiary, Mauritania (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Qatar (2008–2011)
- *Richard B. LeBaron (1951–)
- Ambassador Extraordinary and Plenipotentiary, Kuwait (2004–2007)
- Barry F. Lowenkron (1952–)
- Assistant Secretary of State for Democracy, Human Rights, and Labor (2005–2007)
- *Lewis W. Lucke (1951–)
- Ambassador Extraordinary and Plenipotentiary, Swaziland (2004–2005)
- *Jeffrey John Lunstead (1947–)
- Ambassador Extraordinary and Plenipotentiary, Maldives (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Sri Lanka (2003–2006)
- *David L. Lyon (1951–)
- Ambassador Extraordinary and Plenipotentiary, Fiji (2002–2005)
- Ambassador Extraordinary and Plenipotentiary, Tonga (2002–2005)
- Ambassador Extraordinary and Plenipotentiary, Nauru (2002–2005)
- Ambassador Extraordinary and Plenipotentiary, Tuvalu (2002–2005)
- Ambassador Extraordinary and Plenipotentiary, Kiribati (2003–2005)
- Earle I. Mack (1935–)
- Ambassador Extraordinary and Plenipotentiary, Finland (2004–2005)
- *John F. Maisto (1938–)
- Ambassador Extraordinary and Plenipotentiary, Nicaragua (1993–1996)
- Ambassador Extraordinary and Plenipotentiary, Venezuela (1997–2000)
- Permanent Representative of the U.S.A. to the Organization of American States (Washington) (2003–2006)
- *Michael W. Marine (1947–)
- Chargé d’Affaires ad interim, Fiji (1995)
- Chargé d’Affaires ad interim, Kiribati (1995)
- Chargé d’Affaires ad interim, Tonga (1995)
- Chargé d’Affaires ad interim, Tuvalu (1995)
- Ambassador Extraordinary and Plenipotentiary, Vietnam (2004–2007)
- *R. Niels Marquardt (1954–)
- Ambassador Extraordinary and Plenipotentiary, Equatorial Guinea (2004–2006)
- Ambassador Extraordinary and Plenipotentiary, Cameroon (2004–2007)
- Ambassador Extraordinary and Plenipotentiary, Comoros (2007–2010)
- Ambassador Extraordinary and Plenipotentiary, Madagascar (2007–2010)
- *Carmen Maria Martinez (1950–)
- Chargé d’Affaires, Burma (2005)
- Ambassador Extraordinary and Plenipotentiary, Zambia (2005–2008)
- *Gail Dennise Thomas Mathieu (1951–)
- Ambassador Extraordinary and Plenipotentiary, Niger (2002–2005)
- Ambassador Extraordinary and Plenipotentiary, Namibia (2007–2010)
- Susan Rasinski McCaw (1962–)
- Ambassador Extraordinary and Plenipotentiary, Austria (2005–2007)
- *Sean McCormack (1964–)
- Assistant Secretary of State for Public Affairs (2005–2009)
- William Paul McCormick (1939–)
- Ambassador Extraordinary and Plenipotentiary, Samoa (2005–2008)
- Ambassador Extraordinary and Plenipotentiary, New Zealand (2005–2008)
- *Terence Patrick McCulley (1957–)
- Ambassador Extraordinary and Plenipotentiary, Mali (2005–2008)
- Ambassador Extraordinary and Plenipotentiary, Nigeria (2010–2013)
- Ambassador Extraordinary and Plenipotentiary, Côte d’Ivoire (2013–2016)
- *Jackson C. McDonald (1956–)
- Ambassador Extraordinary and Plenipotentiary, The Gambia (2001–2004)
- Ambassador Extraordinary and Plenipotentiary, Guinea (2004–2007)
- *Douglas L. McElhaney (1947–)
- Ambassador Extraordinary and Plenipotentiary, Bosnia and Herzegovina (2004–2007)
- *James D. McGee (1949–)
- Ambassador Extraordinary and Plenipotentiary, Swaziland (2002–2004)
- Ambassador Extraordinary and Plenipotentiary, Madagascar (2004–2007)
- Ambassador Extraordinary and Plenipotentiary, Comoros (2006)
- Ambassador Extraordinary and Plenipotentiary, Zimbabwe (2007–2009)
- *Roger A. Meece (1949–)
- Ambassador Extraordinary and Plenipotentiary, Malawi (2000–2003)
- Ambassador Extraordinary and Plenipotentiary, Congo (Kinshasa) (2004–2007)
- *Richard Monroe Miles (1937–)
- Ambassador Extraordinary and Plenipotentiary, Azerbaijan (1992–1993)
- Ambassador Extraordinary and Plenipotentiary, Bulgaria (1999–2002)
- Chargé d’Affaires ad interim, Socialist Federal Republic of Yugoslavia (1999)
- Ambassador Extraordinary and Plenipotentiary, Georgia (2002–2005)
- John Rippin Miller (1938–)
- Ambassador at Large (2004–2006)
- *Gillian Arlette Milovanovic (1949–)
- Ambassador Extraordinary and Plenipotentiary, Macedonia (2005–2008)
- Ambassador Extraordinary and Plenipotentiary, Mali (2008–2011)
- Kevin E. Moley (1946–)
- Representative of the U.S.A. to the European Office of the United Nations (Geneva) (2001–2006)
- Assistant Secretary of State for International Organization Affairs (2018)
- *William T. Monroe (1950–)
- Ambassador Extraordinary and Plenipotentiary, Bahrain (2004–2007)
- *Barbara C. Moore (1952–2010)
- Ambassador Extraordinary and Plenipotentiary, Nicaragua (2002–2005)
- Constance Albanese Morella (1931–)
- Representative of the U.S.A. to the Organization for Economic Cooperation and Development (Paris) (2003–2005)
- *James F. Moriarty (1953–)
- Ambassador Extraordinary and Plenipotentiary, Nepal (2004–2007)
- Ambassador Extraordinary and Plenipotentiary, Bangladesh (2008–2011)
- *Greta N. Morris (1947–)
- Ambassador Extraordinary and Plenipotentiary, Marshall Islands (2003–2006)
- David Campbell Mulford (1937–)
- Ambassador Extraordinary and Plenipotentiary, India (2003–2009)
- *Stephen D. Mull (1958–)
- Ambassador Extraordinary and Plenipotentiary, Lithuania (2003–2006)
- Executive Secretary (2009–2012)
- Ambassador Extraordinary and Plenipotentiary, Poland (2012–2015)
- Career Ambassador (2016)
- *Joseph A. Mussomeli (1952–)
- Ambassador Extraordinary and Plenipotentiary, Cambodia (2005–2008)
- Ambassador Extraordinary and Plenipotentiary, Slovenia (2010–2015)
- *John Dimitri Negroponte (1939–)
- Ambassador Extraordinary and Plenipotentiary, Honduras (1981–1985)
- Assistant Secretary of State for Oceans and International Environmental and Scientific Affairs (1985–1987)
- Ambassador Extraordinary and Plenipotentiary, Mexico (1989–1993)
- Ambassador Extraordinary and Plenipotentiary, Philippines (1993–1996)
- Representative of the U.S.A. to the United Nations (2001–2004)
- Ambassador Extraordinary and Plenipotentiary, Iraq (2004–2005)
- Deputy Secretary of State (2007–2009)
- *Wayne E. Neill II (1957–)
- Ambassador Extraordinary and Plenipotentiary, Benin (2003–2006)
- *Ronald E. Neumann (1944–)
- Ambassador Extraordinary and Plenipotentiary, Algeria (1994–1997)
- Ambassador Extraordinary and Plenipotentiary, Bahrain (2001–2004)
- Ambassador Extraordinary and Plenipotentiary, Afghanistan (2005–2007)
- Constance Berry Newman (1935–)
- Assistant Secretary of State for African Affairs (2004–2005)
- James (Jim) Nicholson (1938–)
- Ambassador Extraordinary and Plenipotentiary, Holy See (2001–2005)
- Roger Francisco Noriega (1959–)
- Permanent Representative of the U.S.A. to the Organization of American States (Washington) (2001–2003)
- Assistant Secretary of State for Western Hemisphere Affairs (2003–2005)
- *Victoria Nuland (1961–)
- U.S. Permanent Representative on the Council of the North Atlantic Treaty Organization (2005–2008)
- Assistant Secretary of State for European and Eurasian Affairs (2013–2017)
- Career Ambassador (2016)
- James Curtis Oberwetter (1944–)
- Ambassador Extraordinary and Plenipotentiary, Saudi Arabia (2003–2007)
- Louise Oliver (1944–)
- U.S. Permanent Representative to the United Nations Educational, Scientific and Cultural Organization (2004–2009)
- John D. Ong (1933–)
- Ambassador Extraordinary and Plenipotentiary, Norway (2002–2005)
- *John Malcolm Ordway (1950–)
- Ambassador Extraordinary and Plenipotentiary, Armenia (2001–2004)
- Ambassador Extraordinary and Plenipotentiary, Kazakhstan (2004–2008)
- Chargé d’Affaires ad interim, Kazakhstan (2014)
- *Larry Leon Palmer (1949–)
- Ambassador Extraordinary and Plenipotentiary, Honduras (2002–2005)
- Ambassador Extraordinary and Plenipotentiary, Dominica (2012–2016)
- Ambassador Extraordinary and Plenipotentiary, Barbados (2012–2016)
- Ambassador Extraordinary and Plenipotentiary, Antigua and Barbuda (2012–2016)
- Ambassador Extraordinary and Plenipotentiary, Grenada (2012–2016)
- Ambassador Extraordinary and Plenipotentiary, Saint Vincent and the Grenadines (2012–2016)
- Ambassador Extraordinary and Plenipotentiary, Saint Lucia (2012–2016)
- Ambassador Extraordinary and Plenipotentiary, Saint Kitts and Nevis (2012–2016)
- Ambassador Extraordinary and Plenipotentiary, Venezuela (Nomination of June 24, 2010, returned to the President on December 22, 2010.)
- James W. Pardew (1944–)
- Ambassador Extraordinary and Plenipotentiary, Bulgaria (2002–2005)
- *B. Lynn Pascoe (1943–)
- Ambassador Extraordinary and Plenipotentiary, Malaysia (1998–2001)
- Ambassador Extraordinary and Plenipotentiary, Indonesia (2004–2007)
- *Anne Woods Patterson (1949–)
- Ambassador Extraordinary and Plenipotentiary, El Salvador (1997–2000)
- Ambassador Extraordinary and Plenipotentiary, Colombia (2000–2003)
- Assistant Secretary of State for International Narcotics and Law Enforcement Affairs (2005–2007)
- Ambassador Extraordinary and Plenipotentiary, Pakistan (2007–2010)
- Career Ambassador (2008)
- Ambassador Extraordinary and Plenipotentiary, Egypt (2011–2013)
- Assistant Secretary of State for Near Eastern Affairs (2013–2017)
- *W. Robert Pearson (1943–)
- Executive Secretary (1991–1993)
- Ambassador Extraordinary and Plenipotentiary, Turkey (2000–2003)
- Director General of the Foreign Service (2003–2006)
- *June Carter Perry (1943–)
- Ambassador Extraordinary and Plenipotentiary, Lesotho (2004–2007)
- Ambassador Extraordinary and Plenipotentiary, Sierra Leone (2007–2009)
- *Katherine Hubay Peterson (1949–)
- Ambassador Extraordinary and Plenipotentiary, Lesotho (1998–2001)
- Director of the Foreign Service Institute (2001–2005)
- Ambassador Extraordinary and Plenipotentiary, Botswana (2005–2008)
- *Roger Dwayne Pierce (1951–)
- Ambassador Extraordinary and Plenipotentiary, Cape Verde (2005–2007)
- *Michael Christian Polt (1954–)
- Ambassador Extraordinary and Plenipotentiary, Serbia (2004–2007)
- Ambassador Extraordinary and Plenipotentiary, Estonia (2009–2012)
- Colin Luther Powell (1937–2021)
- Secretary of State (2001–2005)
- Dina Habib Powell (1973–)
- Assistant Secretary of State for Educational and Cultural Affairs (2005–2007)
- John Price (1933–)
- Ambassador Extraordinary and Plenipotentiary, Comoros (2002–2005)
- Ambassador Extraordinary and Plenipotentiary, Seychelles (2002–2005)
- Ambassador Extraordinary and Plenipotentiary, Mauritius (2002–2005)
- Pierre-Richard Prosper (1963–)
- Ambassador at Large (2001–2005)
- *Jon Robert Purnell (1948–)
- Ambassador Extraordinary and Plenipotentiary, Uzbekistan (2003–2007)
- Stephen Geoffrey Rademaker (1959–)
- Assistant Secretary of State for Arms Control (2002–2005)
- *Marguerita Dianne Ragsdale (1948–)
- Ambassador Extraordinary and Plenipotentiary, Djibouti (2003–2006)
- Clark T. Randt Jr. (1945–)
- Ambassador Extraordinary and Plenipotentiary, China (2001–2009)
- *Charles Aaron Ray (1945–)
- Ambassador Extraordinary and Plenipotentiary, Cambodia (2002–2005)
- Ambassador Extraordinary and Plenipotentiary, Zimbabwe (2009–2012)
- Grover Joseph Rees 3rd (1951–)
- Ambassador Extraordinary and Plenipotentiary, Timor-Leste (2002–2006)
- Mitchell Reiss (1957–)
- Director of Policy Planning (2003–2005)
- Michael Retzer (1946–)
- Ambassador Extraordinary and Plenipotentiary, Tanzania (2005–2007)
- *Francis Joseph Ricciardone (1952–)
- Ambassador Extraordinary and Plenipotentiary, Philippines (2002–2005)
- Ambassador Extraordinary and Plenipotentiary, Palau (2002–2005)
- Ambassador Extraordinary and Plenipotentiary, Egypt (2005–2008)
- Ambassador Extraordinary and Plenipotentiary, Turkey (2010–2014)
- Condoleezza Rice (1954–)
- Secretary of State (2005–2009)
- *Charles P. Ries (1951–)
- Ambassador Extraordinary and Plenipotentiary, Greece (2004–2007)
- *Marcie B. Ries (1950–)
- Ambassador Extraordinary and Plenipotentiary, Albania (2004–2007)
- Ambassador Extraordinary and Plenipotentiary, Bulgaria (2012–2015)
- Thomas Riley (1949–)
- Ambassador Extraordinary and Plenipotentiary, Morocco (2003–2008)
- *Thomas Bolling Robertson (1950–)
- Ambassador Extraordinary and Plenipotentiary, Slovenia (2004–2007)
- Christina B. Rocca (1957–)
- Assistant Secretary of State for South and Central Asian Affairs (2001–2006)
- John D. Rood (1955–)
- Ambassador Extraordinary and Plenipotentiary, The Bahamas (2004–2007)
- Francis Rooney (1953–)
- Ambassador Extraordinary and Plenipotentiary, Holy See (2005–2008)
- *Richard Allen Roth (1948–)
- Ambassador Extraordinary and Plenipotentiary, Guinea-Bissau (2002–2005)
- Ambassador Extraordinary and Plenipotentiary, Senegal (2002–2005)
- *Robin Renee Sanders (1954–)
- Ambassador Extraordinary and Plenipotentiary, Congo (Brazzaville) (2002–2005)
- Ambassador Extraordinary and Plenipotentiary, Nigeria (2007–2010)
- John Thomas Schieffer (1947–)
- Ambassador Extraordinary and Plenipotentiary, Australia (2001–2005)
- Ambassador Extraordinary and Plenipotentiary, Japan (2005–2009)
- *Ronald Lewis Schlicher (1958–)
- Chargé d’Affaires ad interim, Lebanon (1996)
- Ambassador Extraordinary and Plenipotentiary, Cyprus (2005–2008)
- Ambassador Extraordinary and Plenipotentiary, Tunisia (Nomination not acted upon by the Senate.)
- Rockwell Anthony Schnabel (1936–)
- Ambassador Extraordinary and Plenipotentiary, Finland (1985–1989)
- Representative of the U.S.A. to the European Union, with the rank and status of Ambassador Extraordinary and Plenipotentiary (2001–2005)
- Gregory L. Schulte (1958–)
- Representative of the U.S.A. to the Vienna Office of the United Nations (Vienna) (2005–2009)
- Representative of the U.S.A. to the International Atomic Energy Agency (Vienna) (2005–2009)
- *Margaret Scobey (1949–)
- Ambassador Extraordinary and Plenipotentiary, Syria (2003–2005)
- Ambassador Extraordinary and Plenipotentiary, Egypt (2008–2011)
- Melvin Floyd Sembler (1930–)
- Ambassador Extraordinary and Plenipotentiary, Australia (1989–1993)
- Ambassador Extraordinary and Plenipotentiary, Nauru (1989–1993)
- Ambassador Extraordinary and Plenipotentiary, Italy (2001–2005)
- *Thomas Alfred Shannon Jr. (1958–)
- Assistant Secretary of State for Western Hemisphere Affairs (2005–2009)
- Ambassador Extraordinary and Plenipotentiary, Brazil (2009–2013)
- Career Ambassador (2012)
- Counselor (2013–2016)
- Under Secretary of State for Political Affairs (2016–2018)
- Secretary of State ad interim (2017)
- Josette Sheeran Shiner (1954–)
- Under Secretary for Economic Growth, Energy, and the Environment (2005–2007)
- Kristen Silverberg (1970–)
- Assistant Secretary of State for International Organization Affairs (2005–2008)
- Representative of the U.S.A. to the European Union, with the rank and status of Ambassador Extraordinary and Plenipotentiary (2008–2009)
- Martin J. Silverstein (1954–)
- Ambassador Extraordinary and Plenipotentiary, Uruguay (2001–2005)
- *Michele Jeanne Sison (1959–)
- Ambassador Extraordinary and Plenipotentiary, United Arab Emirates (2004–2008)
- Ambassador Extraordinary and Plenipotentiary, Lebanon (2008–2010)
- Ambassador Extraordinary and Plenipotentiary, Maldives (2012–2014)
- Ambassador Extraordinary and Plenipotentiary, Sri Lanka (2012–2014)
- Ambassador Extraordinary and Plenipotentiary, Haiti (2018)
- Career Ambassador (2018)
- *Emil M. Skodon (1953–)
- Ambassador Extraordinary and Plenipotentiary, Brunei (2005–2008)
- *Pamela Jo Howell Slutz (1949–)
- Ambassador Extraordinary and Plenipotentiary, Mongolia (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Burundi (2009–2012)
- Clifford M. Sobel (1949–)
- Ambassador Extraordinary and Plenipotentiary, Netherlands (2001–2005)
- Ambassador Extraordinary and Plenipotentiary, Brazil (2006–2009)
- Ronald Spogli (1948–)
- Ambassador Extraordinary and Plenipotentiary, Italy (2005–2009)
- Ambassador Extraordinary and Plenipotentiary, San Marino (2006–2009)
- *Joseph D. Stafford (1950–)
- Ambassador Extraordinary and Plenipotentiary, The Gambia (2004–2007)
- Chargé d’Affaires, Sudan (2014)
- Craig Roberts Stapleton (1945–)
- Ambassador Extraordinary and Plenipotentiary, Czech Republic (2001–2003)
- Ambassador Extraordinary and Plenipotentiary, France (2005–2009)
- Envoy Extraordinary and Minister Plenipotentiary, Monaco (2006–2009)
- *James Curtis Struble (1953–)
- Ambassador Extraordinary and Plenipotentiary, Peru (2003–2007)
- Charles J. Swindells (1942–)
- Ambassador Extraordinary and Plenipotentiary, Samoa (2001–2005)
- Ambassador Extraordinary and Plenipotentiary, New Zealand (2001–2005)
- William Howard Taft IV (1945–)
- U.S. Permanent Representative on the Council of the North Atlantic Treaty Organization (1989–1992)
- Legal Adviser (2001–2005)
- Nicholas F. Taubman (1935–)
- Ambassador Extraordinary and Plenipotentiary, Romania (2005–2008)
- Francis Xavier Taylor (1948–)
- Director of the Bureau of Counterterrorism (2001–2002)
- Ambassador at Large (2001)
- Ambassador at Large (2001–2004)
- Director of the Office of Foreign Missions (2002–2005)
- Assistant Secretary of State for Diplomatic Security (2002–2005)
- *John F. Tefft (1949–)
- Ambassador Extraordinary and Plenipotentiary, Lithuania (2000–2003)
- Ambassador Extraordinary and Plenipotentiary, Georgia (2005–2009)
- Ambassador Extraordinary and Plenipotentiary, Ukraine (2009–2013)
- Ambassador Extraordinary and Plenipotentiary, Russia (2014–2017)
- Peter Terpeluk (1948–2011)
- Ambassador Extraordinary and Plenipotentiary, Luxembourg (2002–2005)
- *Harry Keels Thomas Jr. (1956–)
- Ambassador Extraordinary and Plenipotentiary, Bangladesh (2003–2005)
- Executive Secretary (2005–2007)
- Director General of the Foreign Service (2007–2009)
- Ambassador Extraordinary and Plenipotentiary, Philippines (2010–2013)
- Ambassador Extraordinary and Plenipotentiary, Zimbabwe (2015–2018)
- William Robert Timken Jr. (1938–)
- Ambassador Extraordinary and Plenipotentiary, Germany (2005–2008)
- *Paul A. Trivelli (1953–)
- Ambassador Extraordinary and Plenipotentiary, Nicaragua (2005–2008)
- John F. Turner (1942–)
- Assistant Secretary of State for Oceans and International Environmental and Scientific Affairs (2001–2005)
- Robert H. Tuttle (1947–)
- Ambassador Extraordinary and Plenipotentiary, United Kingdom (2005–2009)
- Chase Untermeyer (1946–)
- Ambassador Extraordinary and Plenipotentiary, Qatar (2004–2007)
- Rodolphe M. Vallee (1960–)
- Ambassador Extraordinary and Plenipotentiary, Slovakia (2005–2007)
- *Carol van Voorst (1952–)
- Ambassador Extraordinary and Plenipotentiary, Iceland (2005–2009)
- *Alexander Russel Vershbow (1952–)
- U.S. Permanent Representative on the Council of the North Atlantic Treaty Organization (1997–2001)
- Ambassador Extraordinary and Plenipotentiary, Russia (2001–2005)
- Ambassador Extraordinary and Plenipotentiary, Korea (2005–2008)
- Anne Louise Wagner (1962–)
- Ambassador Extraordinary and Plenipotentiary, Luxembourg (2005–2009)
- George H. Walker (1931–)
- Ambassador Extraordinary and Plenipotentiary, Hungary (2003–2006)
- *R. Barrie Walkley (1944–)
- Ambassador Extraordinary and Plenipotentiary, Guinea (2001–2004)
- Ambassador Extraordinary and Plenipotentiary, Gabon (2004–2007)
- Ambassador Extraordinary and Plenipotentiary, Sao Tome and Principe (2004–2007)
- Chargé d’Affaires ad interim, South Sudan (2011)
- *Marc M. Wall (1954–)
- Ambassador Extraordinary and Plenipotentiary, Chad (2004–2007)
- Marilyn Ware (1943–)
- Ambassador Extraordinary and Plenipotentiary, Finland (2005–2008)
- *Linda Ellen Watt (1951–)
- Ambassador Extraordinary and Plenipotentiary, Panama (2002–2005)
- *Earl Anthony Wayne (1950–)
- Assistant Secretary of State for Economic, Energy, and Business Affairs (2000–2006)
- Ambassador Extraordinary and Plenipotentiary, Argentina (2006–2009)
- Ambassador Extraordinary and Plenipotentiary, Mexico (2011–2015)
- Career Ambassador (2011)
- *C. David Welch (1953–)
- Chargé d’Affaires ad interim, Saudi Arabia (1994)
- Assistant Secretary of State for International Organization Affairs (1998–2001)
- Ambassador Extraordinary and Plenipotentiary, Egypt (2001–2005)
- Assistant Secretary of State for Near Eastern Affairs (2005–2008)
- Career Ambassador (2008)
- Benson K. Whitney (1956–)
- Ambassador Extraordinary and Plenipotentiary, Norway (2005–2009)
- David Horton Wilkins (1946–)
- Ambassador Extraordinary and Plenipotentiary, Canada (2005–2009)
- Pamela P. Willeford (1950–)
- Ambassador Extraordinary and Plenipotentiary, Switzerland (2003–2006)
- Ambassador Extraordinary and Plenipotentiary, Liechtenstein (2003–2006)
- *Ross L. Wilson (1955–)
- Ambassador Extraordinary and Plenipotentiary, Azerbaijan (2000–2003)
- Ambassador Extraordinary and Plenipotentiary, Turkey (2005–2008)
- *William Braucher Wood (1950–)
- Ambassador Extraordinary and Plenipotentiary, Colombia (2003–2007)
- Ambassador Extraordinary and Plenipotentiary, Afghanistan (2007–2009)
- Aldona Wos (1955–)
- Ambassador Extraordinary and Plenipotentiary, Estonia (2004–2007)
- *Mary Carlin Yates (1946–)
- Ambassador Extraordinary and Plenipotentiary, Burundi (1999–2002)
- Ambassador Extraordinary and Plenipotentiary, Ghana (2002–2005)
- Chargé d’Affaires, Sudan (2012)
- *James Howard Yellin (1938–)
- Ambassador Extraordinary and Plenipotentiary, Burundi (2002–2005)
- *Stephen M. Young (1951–)
- Ambassador Extraordinary and Plenipotentiary, Kyrgyzstan (2003–2005)
- *Marie L. Yovanovitch (1958–)
- Ambassador Extraordinary and Plenipotentiary, Kyrgyzstan (2004–2008)
- Ambassador Extraordinary and Plenipotentiary, Armenia (2008–2011)
- Ambassador Extraordinary and Plenipotentiary, Ukraine (2016–2019)
- Philip D. Zelikow (1954–)
- Counselor (2005–2007)
- Robert B. Zoellick (1953–)
- Counselor (1989–1992)
- Under Secretary for Economic Growth, Energy, and the Environment (1991–1992)
- Deputy Secretary of State (2005–2006)